Properties of NiO thin films deposited by intermittent spray pyrolysis process
Identifieur interne : 000185 ( France/Analysis ); précédent : 000184; suivant : 000186Properties of NiO thin films deposited by intermittent spray pyrolysis process
Auteurs : B. A. Reguig [Algérie] ; A. Khelil [Algérie] ; L. Cattin [France] ; M. Morsli [France] ; J. C. Bernede [France]Source :
- Applied surface science [ 0169-4332 ] ; 2007.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Composé minéral.
English descriptors
- KwdEn :
Abstract
NiO thin films have been grown on glass substrates by intermittent spray pyrolysis deposition of NiCl2.6H2O diluted in distilled water, using a simple "perfume atomizer". The effect of the solution molarity on their properties was studied and compared to those of NiO thin films deposited with a classical spray system. It is shown that NiO thin films crystallized in the NiO structure are achieved after deposition. Whatever the precursor molarity, the grain size is around 25-30 nm. The crystallites are preferentially oriented along the (111) direction. All the films are p-type. However, the thickness and the conductivity of the NiO films depend on the precursor contraction. By comparison with the properties of films deposited by classical spray technique, it is shown that the critical precursor concentration, which induces strong thin films properties perturbations, is higher when a perfume atomizer is used. This broader stability domain can be attributed to better chlorides decomposition during the rest time used in the perfume atomizer technique.
Affiliations:
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Pascal:07-0232109Le document en format XML
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<term>Transition element compounds</term>
<term>p type semiconductor</term>
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<term>Pyrolyse</term>
<term>Semiconducteur type p</term>
<term>Nickel oxyde</term>
<term>NiO</term>
<term>Ni O</term>
<term>Composé minéral</term>
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<front><div type="abstract" xml:lang="en">NiO thin films have been grown on glass substrates by intermittent spray pyrolysis deposition of NiCl<sub>2</sub>
.6H<sub>2</sub>
O diluted in distilled water, using a simple "perfume atomizer". The effect of the solution molarity on their properties was studied and compared to those of NiO thin films deposited with a classical spray system. It is shown that NiO thin films crystallized in the NiO structure are achieved after deposition. Whatever the precursor molarity, the grain size is around 25-30 nm. The crystallites are preferentially oriented along the (111) direction. All the films are p-type. However, the thickness and the conductivity of the NiO films depend on the precursor contraction. By comparison with the properties of films deposited by classical spray technique, it is shown that the critical precursor concentration, which induces strong thin films properties perturbations, is higher when a perfume atomizer is used. This broader stability domain can be attributed to better chlorides decomposition during the rest time used in the perfume atomizer technique.</div>
</front>
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